Crystal structure of (Z)-2-(1-benzyl-2- oxoindolin-3-ylidene)-N-phenylhydrazine-1-carbothioamide

Simple item page
dc.contributor.authorVimala, G
dc.contributor.authorHaribabu, J
dc.contributor.authorKarvembu, R
dc.contributor.authorPhani Kumar, B.V.N
dc.contributor.authorSubbiahPandi, A
dc.date.accessioned2026-08-16T06:35:54Z
dc.date.available2026-08-16T06:35:54Z
dc.date.issued2015-02-07
dc.description.abstractThe title compound, C22H18N4OS, crystallized with four independent molecules (A, B, C and D) in the asymmetric unit. All four molecules have a Z conformation about the C=N bond with the benzyl ring being inclined to the indoline ring mean planes by 73.4 (2), 77.9 (2), 73.2 (2) and 77.2 (2)° in molecules A, B, C and D, respectively. In molecules A and B, the phenyl ring is inclined to the mean plane of the indoline ring mean plane by 12.0 (2) and 12.2 (2)°, respectively. However, in molecules C and D, the same dihedral angles are larger, viz. 37.3 (2) and 36.4 (2)°, respectively. Consequently, the benzyl and phenyl rings are almost normal to one another in molecules A and B [dihedral angles = 80.3 (3) and 87.1 (3)°, respectively], while in molecules C and D, the same dihedral angles are only 48.8 (2) and 43.8 (3)°, respectively. There is an intramolecular N - H⋯O hydrogen bond in each molecule with an S(6) ring motif. There are also short intramolecular N - H⋯N and C - H⋯S contacts in each molecule. In the crystal, molecules are linked via C - H⋯S hydrogen bonds and C - H⋯π interactions, forming a three-dimensional structure. The crystal was refined as a non-merohedral twin with a final BASF value of 0.110 (1).
dc.identifier.issn2056-9890
dc.identifier.urihttps://doi.org/10.1107/S2056989015002248
dc.identifier.urihttp://nitt.ndl.gov.in/handle/123456789/192
dc.language.isoen
dc.publisherInternational Union of Crystallography
dc.relation.ispartofseriesActa Crystallographica Section E: Structure Reports Online; Vol. 71 / No. 3
dc.titleCrystal structure of (Z)-2-(1-benzyl-2- oxoindolin-3-ylidene)-N-phenylhydrazine-1-carbothioamide
dc.typeArticle
Files
Original bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
Crystal structure of (Z)-2-(1-benzyl-2-oxoindolin-3-ylidene)-N-phenylhydra-zine-1-carbothioamide.pdf
Size:
531.37 KB
Format:
Adobe Portable Document Format
Download
License bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
licence .pdf
Size:
6.75 KB
Format:
Adobe Portable Document Format
Description:
Download
Collections
Journal Articles