Bis(3-benzoyl-1,1-disecbutyl-thioureato- 2 O,S)palladium(II)
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Date
2011-09-17
Journal Title
Journal ISSN
Volume Title
Publisher
International Union of Crystallography
Abstract
The complex molecule of the title complex, [Pd(C 16H 23N 2OS) 2], is completed by crystallographic twofold symmetry with the metal atom lying on the rotation axis. The Pd II atom exists within a slightly distorted squareplanar geometry defined by a cis-O 2S 2 donor set. The dihedral angle formed between the mean planes of the symmetry-related six-membered chelate rings is 12.88 (7)° and the bond lengths within the rings are indicative of significant electron delocalization. In the crystal, molecules aggregate into dimers linked by four C-H⋯O interactions.