1-Benzoyl-3-methyl-3-pentylthiourea
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Date
2011-04-16
Journal Title
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Publisher
International Union of Crystallography
Abstract
Two independent molecules comprise the asymmetric unit of the title compound, C14H20N2OS. These differ in the relative orientations of the pentyl chains [C-C-C-C torsion angles = 176.7 (3) and 176.4 (3)°]. Significant twists are evident in each molecule, the dihedral angles formed between the thiourea and amide residues being 53.47 (17) and 55.81 (17)°. In the crystal, each molecule self-associates via a centrosymmetric eight-membered {⋯HNC S}2 synthon, and these are connected into a supramolecular chain along [110] via C-H⋯O contacts. Disorder is noted for one of the independent molecules in that two orientations (50:50) were resolved for its benzene ring.