3-Benzoyl-1,1-dibenzylthiourea
| dc.contributor.author | Gunasekaran, N | |
| dc.contributor.author | Karvembu, R | |
| dc.contributor.author | Ng, Seik Weng | |
| dc.contributor.author | Tiekink, Edward R. T. | |
| dc.date.accessioned | 2026-08-19T09:33:10Z | |
| dc.date.available | 2026-08-19T09:33:10Z | |
| dc.date.issued | 2010-09-18 | |
| dc.description.abstract | Two independent thio-urea molecules comprise the asymmetric unit of the title compound, C22H20N2OS. The central N-C(=S)N(H)C(=O) atoms in each molecule are virtually superimposable and each is twisted [C - N - C - S torsion angles = 121.3 (3) and -62.3 (4)°]. The molecules differ only in terms of the relative orientations of the benzyl benzene rings [major difference between the C - N - C - C torsion angles of -146.6 (3) and -132.9 (3)°]. The presence of N - H⋯S hydrogen bonding leads to the formation of supra-molecular chains along the a axis. These are consolidated in the crystal packing by C - H⋯O interactions. The crystal was found to be a combined non-merohedral and racemic twin (twin law 1̄00/01̄0/001), with the fractional contribution of the minor components being approximately 9 and 28%. | |
| dc.identifier.issn | 1600-5368 | |
| dc.identifier.uri | https://doi.org/10.1107/S1600536810036226 | |
| dc.identifier.uri | http://nitt.ndl.gov.in/handle/123456789/211 | |
| dc.language.iso | en | |
| dc.publisher | International Union of Crystallography | |
| dc.relation.ispartofseries | Acta Crystallographica Section E: Structure Reports Online; Vol. 66/ No. 10 | |
| dc.title | 3-Benzoyl-1,1-dibenzylthiourea | |
| dc.type | Article |