1-Benzoyl-3,3-bis(propan-2-yl)thiourea
No Thumbnail Available
Date
2010-07-24
Journal Title
Journal ISSN
Volume Title
Publisher
International Union of Crystallography
Abstract
Two independent thiourea derivatives comprise the asymmetric unit of the title compound, C14H20N2OS. The major difference between the mol-ecules relates to a twist in the relative orientation of the benzene rings [torsion angles = 4.5 (2) and -19.9 (2)° for the two independent mol-ecules]. The thio-carbonyl and carbonyl groups lie to opposite sides of the mol-ecule as there are twists about the central N - S bond [torsion angles = 83.90 (15) and 81.77 (15)°]. Supra-molecular chains extending parallel to [101] with a stepped topology and mediated by N - H⋯O hydrogen bonding feature in the crystal structure. C - H⋯O and C - H⋯π inter-actions are also present.